At your risk.
All safety measures should be followed.
Any voltage or current can be dangerous.
This is an excellent video from YouTube channel
JoulesperCoulomb
https://m.youtube.com/watch?v=u_NnU48bmv4
(By the way energy per charge is by definition electric field potential measured in volts).
The definition of electric field potential difference is one of the most difficult to understand definitions in physics.
Some of the great books on our planet are
Electricity and Magnetism - Purcel or
Feynman Lectures on Physics - Feynman, Leigton, Sands
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